Abstract
High performance ferroelectric materials have attracted more attention due to its superior dielectric, piezoelectric, and electrostrictive properties. A sol-gel synthesis technique was used to prepare the perovskite Pb(Nbx(Zr0.52Ti0.48)(1−x))O3 (where x = 0, 0.02) nanoceramics. X-ray powder diffraction studies confirm the successful formation of perovskite (ABO3) structure of the ceramics without presence of pyrochlore (A3B4O13) phase which is unwanted for PZT system. Also, the thermogravimetric studies were conducted to confirm the structure formation at elevated temperature. The relative permittivity increases with doping of niobium and curie temperature decreases for the same. The dielectric study of the undoped PZT at the temperature of 500 °C and Nb doped PZT at the temperature of 350 °C for the same frequency of 100 Hz give relative permittivity, εr ≈ 11000 and εr ≈ 1850 respectively. An Arrhenius plot was used to calculate the activation energy and it was found to be 0.210, and 0.161 eV for the undoped and Nb-doped PZT ceramics respectively. The maximum remnant polarization is 1.21 μC/cm2 for niobium doped PZT and 0.16 μC/cm2 for undoped PZT for the applied voltage of 1500 V. The primary goal of this research is to determine how doping with niobium affects the dielectric and ferroelectric properties of PZT (52/48).
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
