Abstract

The title complex, [Ir2(μ-Br)2(C8H12)2], displays a dinuclear structure with bridging Br atoms, generated by twofold symmetry. The coordination geometry around the Ir atom is pseudo-square-planar, involving two Br atoms and two η2 C=C bonds. The Ir2(μ-Br)2 core shows a bent geometry with a hinge angle of 101.58 (3)°.

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