Abstract
The title complex, [Hg2Br4(C18H22S2)]n, has a chain structure. Two bridging Br atoms and two terminal Br atoms coordinate to two HgII atoms to form a (HgBr2)2 dimer, and the 1,4-bis(benzylsulfanyl)butane ligands bridge the (HgBr2)2 dimers to form a one-dimensional chain. The dimer and butane ligand are each located on inversion centers. HgII adopts a tetrahedral geometry formed by three Br and one S atoms.
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