Abstract
Commercially available activated carbon fibers (ACFs) were modified further by a chemical activation method to obtain superior CO2 adsorption capacity. The relationship between the pore structure of the modified ACF and the CO2 adsorption behaviors was investigated. Chemical activation (with KOH at a fixed activation temperature of 900°C for 1h and various KOH/ACF weight ratios ranging from 1 to 4) of ACF increased the total pore volume and specific surface area to 1.124cm3g−1 (KOH/ACF weight ratio of 2) and 2318m2g−1 (KOH/ACF weight ratio of 4), respectively. Compared to ACF, the total pore volume and specific surface area were improved by factors of 2.5 and 2.3, respectively. Interestingly, the highest CO2 adsorption capacity of 250mgg−1 at 298K and 1bar was observed at a KOH/ACF weight ratio of 3. The modified ACF had the narrowest microporosity ranging from 0.5 to 0.7nm. Therefore, the increase in CO2 adsorption capacity after chemical activation is closely related to the narrower pore size distribution rather than the total or micropore volume and specific surface area.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
