Abstract

By considering a superimposed, uniform electric field E polarized along the observation direction and neglecting ionic perturbation, we obtain theoretical profiles showing a forbidden peak higher than the allowed one, just as in experimental profiles. We find best agreement for | E | = 160 kV cm −1 , N e = 3 × 10 17 cm −3. These results imply Li, K, and Cl concentrations (atoms+ions) close to those of the electrolytic bath and a temperature below 6700 K. Ionic perturbations must be studied by leaving off the quasi-static ionic field concept.

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