Abstract

AbstractThe coefficient of the term linearly dependent on K, αj in the phase shift is calculated from the theoretical phase functions of Teo and Lee and from experimental extended X‐ray absorption fine structure (EXAFS) data for 3 d transition metal systems of manganese, cobalt, and copper. Attempts are made to explain the behaviour of the phase shift of a given atom pair in different chemical surroundings. The dependence of αj on chemical shift and partial charge is also studied.

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