DC and high-frequency conductivity of the organic metals [formula omitted]-(BEDT-TTF) 2SF 5RSO 3 (R = CH 2CF 2 and CHF)

Abstract

The temperature dependences of the electric-transport properties of the two-dimensional organic conductors β ″ -(BEDT-TTF) 2SF 5CH 2CF 2SO 3, β ″ -(d 8-BEDT-TTF) 2SF 5CH 2CF 2SO 3, and β ″ -(d 8-BEDT-TTF) 2SF 5CH 2CF 2SO 3 are measured by dc methods in and perpendicular to the highly conducting plane. Microwave measurements are performed at 24 and 33.5 GHz to probe the high-frequency behavior from room temperature down to 2 K. Superconductivity is observed in β ″ -(BEDT-TTF) 2SF 5CH 2CF 2SO 3 and its deuterated analogue. Although all the compounds remain metallic down to low-temperatures, they are close to a charge-order transition. This leads to deviations from a simple Drude behavior of the optical conductivity which become obvious already in the microwave range. In β ″ -(BEDT-TTF) 2SF 5CH 2CF 2SO 3, for instance, charge fluctuations cause an increase in microwave resistivity for T < 20 K which is not detected in dc measurements. β ″ -(BEDT-TTF) 2SF 5CHFSO 3 exhibits a simple metallic behavior at all frequencies. In the dc transport, however, we observe indications of localization in the perpendicular direction.