Abstract
The stability constants of the complexes of α-cyclodextrin and 4-methyl-, 4-nitro-, 4-sulfonato- and 3-chloro-substituted perbenzoic acids, perbenzoates and benzoates, but not benzoic acids, show linear free energy relationships. In contrast to α-cyclodextrin, the stability constants of the β-cyclodextrin complexes of perbenzoic acid and benzoic acids do show the same trend. The stability constants are discussed in terms of the orientation of the guest species in the cyclodextrin cavity.
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