Cs2AgBiBr6 single-crystal X-ray detectors with a low detection limit

Abstract

Sensitive X-ray detection is crucial for medical diagnosis, industrial inspection and scientific research. The recently described hybrid lead halide perovskites have demonstrated low-cost fabrication and outstanding performance for direct X-ray detection, but they all contain toxic Pb in a soluble form. Here, we report sensitive X-ray detectors using solution-processed double perovskite Cs2AgBiBr6 single crystals. Through thermal annealing and surface treatment, we largely eliminate Ag+/Bi3+ disordering and improve the crystal resistivity, resulting in a detector with a minimum detectable dose rate as low as 59.7 nGyair s−1, comparable to the latest record of 0.036 μGyair s−1 using CH3NH3PbBr3 single crystals. Suppressed ion migration in Cs2AgBiBr6 permits relatively large external bias, guaranteeing efficient charge collection without a substantial increase in noise current and thus enabling the low detection limit. Double perovskite Cs2AgBiBr6 single crystals are used to make a sensitive X-ray detector. The device exhibits a high sensitivity of 105 µC Gyair −1 cm−2 and a low detection limit of 59.7 nGyairs−1, and demonstrates long-term operational stability.