Abstract

The crystal structure of the title complex determined from three-dimensional diffractometer data. Z= 4 in an orthorhambic unit cell having a= 12·271, b= 9·550, c= 15·719 A, and space group P212121. Full-matrix least-squares refinement based on 887 observations has led to R 0·048 for the correct absolute configuration of the molecule.The sodium ion is surrounded by a pentagonal pyramid of oxygen atoms. The base is formed by those of the cyclic ether with Na–O 2·35(1)–2·43(1)A and the sodium ion is 0·75 A from this plane towards the apical water molecule, Na–O 2·29(1)A. The iodide ion does not interact with the sodium ion but may form hydrogen bonds to water molecules [O⋯I 3·47(1) and 3·51(1)A], linking the complexes in chains along the b-axis of the crystal.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.