Abstract

Marcus Inverted Region In article number 2200637, Christian A. Nijhuis, Damien Thompson, Enrique Del Barco, and co-workers demonstrate that the mechanism of charge transport can be deliberately switched between the normal and Marcus Inverted regions by controlling the molecule–electrode coupling strength in a series of molecules. The cover shows two almost identical junctions. The only difference is one CH2 which lowers molecule-electrode coupling strength pushing the junctions from direct coherent tunnelling to hopping in the Marcus Inverted region. This ability can improve the energy efficiency of molecular devices. Image credit: Niels van der Velde.

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