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https://doi.org/10.1055/s-0035-1562491
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Cite Journal: Synthesis |  Publication Date: Jun 29, 2016 |
 Citations: 1 |
Affiliation: Sichuan University, Green Chemistry, China Pharmaceutical University
The catecholic ketal core substructure of trichotomone, a dimeric abietane-type diterpenoid, was constructed. Key elements of the synthesis include an Ullmann condensation between a phenol and phenyl bromide, and the final 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ)-mediated oxidative dearomatization/ketalization reaction.
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