Abstract
The preparation of the new chelated complexes [(msdp)M(CO)4][msdp = 1,3-bis(methylseleno)-2,2-dimethyl-propane; M = Cr, Mo, or W] and their temperature-dependent 1H n.m.r. spectra are reported. The well-resolved n.m.r. spectra are interpreted by considering total inversion of the six-membered ring system and thermodynamic parameters, obtained by n.m.r. line-shape fitting techniques, are reported for the ring inversions.
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