Abstract
The diamine Me2NCH2NMe2 (tmmn) is capable of forming simple adducts with most metal(II) ions of the first transition series, but with nickel and cobalt a variety of additional products can be obtained from its reaction with the dihalides. The diamine may be monodentate or bidentate, it may (formally) lose a hydride to generate a cation, and each N–C bond may break, generating new products containing additional methyl groups or the ions (Me2NH2)+ or (Me2NCH2)+.
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