Abstract

The far-i.r. spectra and, where appropriate, the n.m.r. and e.s.r. spectra of the complexes [MX4L2][M = Re, Os, Ir, or Pt; X = Cl or Br; L = mono(tertiary phosphine) or mono(tertiary arsine)] and [MX3L3][M = Re, Ru, Os, or Ir; X = Cl or Br; L = mono(tertiary phosphine) or mono(tertiary arsine)] are described. The former group generally have trans-configurations and the latter meridional.

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