Combustion Characteristics and Performance of Nanoflower Structure AlB2@AP Energetic Composites

Abstract

ABSTRACT Boron-based solids have garnered significant attention due to their high calorific value. However, during combustion, the formation of boron oxide (B₂O₃) on the surface hinders the interaction between the oxidizing components and the internal active boron (B), thereby limiting its reactivity and combustion efficiency. Modifying boron-based solids represents an effective strategy for overcoming the limitations associated with fuel energy release efficiency. In this study, a shell-structured AlB₂@AP composite was designed and fabricated utilizing etching and recrystallization methods. The structure comprises AlB₂ as the core, B as the middle shell, and AP as the embedded outer shell. The key strategy involves employing an etching process to augment the reactive surface area of boron on the aluminum diboride surface, while also coating it with ammonium perchlorate (AP) to enhance the composite particles. This innovative approach demonstrates that the etching method can effectively utilize the boron present in AlB₂. The composite particles were characterized and analyzed for morphology employing a scanning electron microscope and X-ray techniques. Thermal analysis indicated that the decomposition stage of AP facilitated the oxidation of etched AlB₂, moreover, as the AP coating content increased, the temperature at which vigorous reactions initiated occurred earlier. In combustion experiments, the maximum combustion temperatures of AlB₂@10AP, AlB₂@20AP, and AlB₂@30AP increased by 36.4%, 15.1%, and 3.8%, respectively. The combustion formulation prepared with elemental boron exhibited different characteristics. The average combustion temperatures increased by 33.1%, 23.4%, and 14.4%, respectively. The combustion durations were reduced by 60.8%, 33.7%, and 31.7%, respectively. AlB2@AP is anticipated to further enhance its applications in propellants, explosives, and pyrotechnics.