Cluster Analysis for Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans Concentrations in Southern Taiwan

Abstract

This study investigates the characteristics of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in the ambient air of two municipal solid waste incinerators (MSWIs: GS and RW) and a coal-fired power plant (PW) in the Kaohsiung County (KC) area in Taiwan. The results show that the toxic equivalency (TEQ) concentration in the flue gas of GS and RW averaged 0.090 and 0.044 ng international toxic equivalents (I-TEQ)/N·m3, respectively. The TEQ concentration in the flue gas of PW averaged 0.050 ng I-TEQ/N·m3. All PCDD/Fs concentrations from the stack flue gas are lower than the Taiwan Environmental Protection Administration emission standard. Furthermore, the mean I-TEQ concentration in the ambient atmosphere ranged from approximately 0.019 to 0.165 pg I-TEQ/N·m3, much lower than the environmental quality standards for dioxins in Japan (0.6 pg TEQ/N·m3). This work classified all sampling sites into three clusters according to k-means cluster analysis. The result shows a probable direct correlation between the GS incinerator and site C. Although the concentration from the PW plant did not exceed the emission standard, it was much higher than that in Fernández-Martínez’s study. For proper environmental management of dioxins, establishing a complete emission inventory of PCDD/Fs is necessary. The government of Taiwan should particularly pay more attention to power plants to address the information shortage.