Abstract
Circular dichroism spectra of the optically active cyclopropane hydrocarbons (1a) and (2), measured over a range of temperatures, showed these compounds to be configurationally identical. The c.d. spectrum was found to consist of two overlapping exciton pairs, corresponding to an equilibrium mixture of two solution conformers, for which thermodynamic parameters were calculated.
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Schedule a callMore From: Journal of the Chemical Society, Perkin Transactions 2
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