Chemical and mineralogical variability of sediment in a Quaternary aquifer from Huaihe River Basin, China: Implications for groundwater arsenic source and its mobilization

Abstract

Arsenic (As) is a conspicuous contaminant, and exposure to this element through contaminated drinking groundwater poses a significant challenge to public health. Geogenic groundwater arsenic is associated with sedimentary setting. This work concentrates on the investigation of lithology, elemental abundance and mineralogical compositions about the arsenic profile and its effect to the groundwater from Huaihe River Basin, China. There are 90 sediment samples from the borehole at the field monitoring sites were collected and analyzed. The results reveal that sedimentary concentrations of As, Fe, Mn, S, Al, N, organic carbon and mineralogical compositions vary across the Quaternary aquifer. Arsenic abundance of sediments is 10.63 ± 0.56 mg/kg, and peak As concentrations occur between 59.0 m and 64.8 m in fine particle sediments. The specific higher As concentrations in sedimentary aquifer are concordant with arsenic-rich groundwater around the investigated borehole. Fe, Mn, and Al depth profiles follow similar tendency to those of As. Sedimentary As concentrations are significantly correlated to Fe, Al, and Mn concentrations, but are not correlated to organic carbon and S concentrations. Arsenic probably exists in the form of non-crystalline colloids, and Fe, Al minerals are potential host minerals for arsenic. Under alkaline conditions, groundwater arsenic is released and enriched within the Quaternary aquifer by reductive dissolution of As-hosting Fe and Al minerals.