Characterization of polyurethane foam prepared by using starch as polyol

Abstract

AbstractPolyurethane foams were prepared using starch as a main component of polyols and their structural, mechanical, and absorbing properties for organic solvents were investigated. Fourier transform infrared spectra showed that urethane linkage was formed by the reactions between NCO of diisocyanates and OH of polyols. When polyurethane foams were prepared at high molar ratio of NCO/OH, the unreacted NCO groups were detected. Also, urea linkage was formed by the reaction between diisocyanate and water, which was used as the foaming agent. The micrographs showed that the polyurethane foams had closed‐cell structure, of which the cell size increased with NCO/OH molar ratio. The density of polyurethane foams increased with molecular weight of polyethylene glycol. The compressive moduli of polyurethane foams increased with NCO/OH molar ratio. Polyurethane foams prepared using toluene‐2,4‐diisocyanate as diisocyanate had the highest modulus, while those prepared using hexamethylene diisocyanate had the lowest modulus. In case of the absorbency for the organic solvents, the polyurethane foams prepared at NCO/OH molar ratio of 0.8 had the maximum absorbency. Among several organic solvents, the absorbency for dimethyl sulfoxide was the highest, while the absorbency for tetrahydrofuran was the lowest. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 1544–1553, 2007