Abstract
This study examines the effects of sputter deposition growth conditions on IrO2 thin films developed as electrode layers for Pb(ZrxTi1-x)O3 piezoelectric Micro-Electro-Mechanical Systems applications. For IrO2 thin-film bottom electrodes sputter deposited on {100}-textured, rutile structure, TiO2 template layers, the effects of substrate temperature, Ar and O2 flow rates, and post-deposition anneal were studied. Additionally, the impact of various IrO2/Pt bilayer structures on electrode properties were investigated. IrO2 bottom electrodes grown on 100-oriented TiO2 at 500°C with an Ar flow rate of 100sccm, O2 flow rate of 60sccm, and a nominal 100nm thickness exhibited a film sheet resistance of 9.2±0.2Ω/sq., surface roughness of 2.3±0.1nm measured over a 2μm×2μm area, and a rutile structure, preferred-{100} crystalline fiber texture normal to the substrate plane. Furnace-anneal treatments on this electrode at 650°C for 30min in 3 SLM O2 improved its sheet resistance to 7.5±0.2Ω/sq., and surface roughness was 4.0±0.1nm. Bilayers of IrO2/Pt grown on TiO2, with IrO2 and Pt thicknesses in the 0–100nm range, were sputter deposited at 500°C. The electrodes had composite sheet resistances in the range of 1.34±0.03Ω/sq. to 9.92±0.25Ω/sq., and surface roughnesses ranging from 1.5±0.1nm to 2.0±0.1nm for 2μm×2μm measurement areas. Scanning Transmission Electron Microscopy verified preferred IrO2 and Pt crystalline fiber textures of {100} and {111}, respectively.
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