Abstract
Cr-doped titanium oxide (Cr/TiO 2) thin films were deposited on stainless steel and glass substrates by using the cathodic arc deposition technique. The characteristics of undoped and Cr-doped TiO 2 thin films were compared by using several analytical approaches. The undoped TiO 2 film as an as-deposited coating had an anatase structure, while the Cr/TiO 2 film had an amorphous structure, as revealed by X-ray diffraction. After 3 h of heat treatment at 450 °C, the undoped and Cr-doped titanium oxide films became mixed anatase and rutile phases. The microstructure observed under a scanning electron microscope of the Cr-doped TiO 2 film was more compact than that of the undoped film. UV–VIS spectroscopy indicated that chromium doping shifted the absorption edge of the titanium oxide film from the UV region to the visible region. Chromium doping extends the optical absorption range to the visible region and reduces the optical band gap of as-deposited films from 3.2 to 2.2 eV. The drop in the water contact angle from 28° to zero following visible light irradiation implies that the Cr/TiO 2 thin film becomes a better photocatalytic material because of better hydrophilic property.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.