Cellulose levulinate ester as a robust building block for the synthesis of fully biobased functional cellulose esters

Abstract

Facile modification of cellulose or cellulosic derivatives is one of the important strategies to prepare materials with targeted properties, multifunctionality, thus extending their applications in various fields. Cellulose levulinate ester (CLE) has the structural advantage of acetyl propyl ketone moiety pendant, on which fully biobased cellulose levulinate ester derivatives (CLEDs) have been successfully designed and prepared via aldol condensation reaction of CLE with lignin-derived phenolic aldehydes catalyzed by DL-proline. The structure of CLEDs are featured by a phenolic α,β-unsaturated ketone structure, thus endowing them with good UV absorption properties, excellent antioxidant activity, fluorescence properties and satisfactory biocompatibility. The utility of this aldol reaction strategy, together with the facile tunable substitution degree of cellulose levulinate ester and the diversity of aldehydes, can provide potentially a large spectrum of structurally diverse functionalized cellulosic polymers and create new avenues to advanced polymeric architectures.