Wood-Derived Polymers from Olefin-Functionalized Lignin and Ethyl Cellulose via Thiol-Ene Click Chemistry.

Abstract

Lignin and cellulose derivatives have vast potential to be applied in polymer materials. The preparation of cellulose and lignin derivatives through esterification modification is an important method to endow cellulose and lignin with good reactivity, processability and functionality. In this study, ethyl cellulose and lignin are modified via esterification to prepare olefin-functionalized ethyl cellulose and lignin, which are further used to prepare cellulose and lignin cross-linker polymers via thiol-ene click chemistry. The results show that the olefin group concentration in olefin-functionalized ethyl cellulose and lignin reached 2.8096 mmol/g and 3.7000 mmol/g. The tensile stress at break of the cellulose cross-linked polymers reached 23.59 MPa. The gradual enhancement in mechanical properties is positively correlated with the olefin group concentration. The existence of ester groups in the cross-linked polymers and degradation products makes them more thermally stable. In addition, the microstructure and pyrolysis gas composition are also investigated in this paper. This research is of vast significance to the chemical modification and practical application of lignin and cellulose.