Abstract
The title compound, [Ni(C5HN2O4)(C10H8N2)]n, is isotypic with its CoII and ZnII analogues. The asymmetric unit contains two crystallographically independent monomer units with similar geometry. The NiII cations have a distorted octahedral environment formed by two carboxylate O atoms and by four N atoms, two of which belong to the 2,2′-bipyridine ligands and two to different imidazole rings. One imidazole-4,5-carboxylate ligand is connected to two NiII cations, which results in the formation of one-dimensional zigzag chains parallel to [010].
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