Abstract
In the title compound, [Ni(NCS)2(CH3CN)2]n, the NiII cation is coordinated by two N-bonded and two S-bonded thiocyanate anions, as well as two acetonitrile molecules in an octahedral NiN4S2 coordination mode. The asymmetric unit comprises one nickel cation, two thiocyanate anions and two actonitrile molecules. In the crystal, the NiII cations are connected by bridging thiocyanate anions into a three-dimensional coordination network.
Highlights
In the title compound, [Ni(NCS)2(CH3CN)2]n, the NiII cation is coordinated by two N-bonded and two S-bonded thiocyanate anions, as well as two acetonitrile molecules in an octahedral NiN4S2 coordination mode
The NiII cations are connected by bridging thiocyanate anions into a threedimensional coordination network
Symmetry codes: (i) x−1/2, −y+3/2, −z+1; (ii) −x, y−1/2, −z+3/2; (iii) −x, y+1/2, −z+3/2; (iv) x+1/2, −y+3/2, −z+1
Summary
Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-EythStrasse 2, 24098 Kiel, Germany. R factor = 0.027; wR factor = 0.051; data-to-parameter ratio = 22.5. In the title compound, [Ni(NCS)2(CH3CN)2]n, the NiII cation is coordinated by two N-bonded and two S-bonded thiocyanate anions, as well as two acetonitrile molecules in an octahedral NiN4S2 coordination mode. The asymmetric unit comprises one nickel cation, two thiocyanate anions and two actonitrile molecules. The NiII cations are connected by bridging thiocyanate anions into a threedimensional coordination network
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