Catalytic oxidation of O-phenylenediamine by silver nanoparticles for resonance Rayleigh scattering detection of mercury (II) in water samples

Abstract

In this study, a facile nanoparticle catalytic sensor for resonance Rayleigh scattering quantification of mercury (II) ion was developed. The developed approach is relied on the selective inhibition of the peroxidase-like activity of polyvinylpyrrolidone-stabilized silver nanoparticles (PVP-Ag-NPs) by mercury (II) ions. The synthesized PVP-Ag-NPs oxidize the aqueous solution of O-Phenylenediamine (colorless) to 2,3-phenazinediamine (bright yellow) and their resonance Rayleigh scattering (RRS) activity was completely suppressed. When mercury (II) was introduced, the RRS activity of PVP-Ag-NPs was turned on combined with a reduction of the intensity of the yellow color. The enhancement in the RRS intensity was related to the concentration of mercury (II) in the linear range of 10–2000 nM. The smaller size (4.5 nm), the large surface area and the uniform size (PDI = 0.379) of the synthesized PVP-Ag-NPs offered a higher chance for interaction between mercury (II) and PVP-Ag-NPs with the advantages of high sensitivity (LOD = 4 nM) and excellent selectivity for mercury (II) detection over several metals and anions.