Abstract
The luminescent materials CaAl2O4:Mn4+ and CaAl2O4:Mn2+ were synthesized by solid state reaction method. The red luminescence of CaAl2O4:Mn4+ shows an asymmetric broad band peaking at 650 nm, respectively to the characteristic luminescence of Mn4+ ions. The emission spectrum of CaAl2O4:Mn2+ shows a broad green emission band centering at 545 nm respectively to the characteristic luminescence of Mn2+ ions. By doping different outer shells in the same host lattice, the ionic interaction between ions and the host lattice are also different. The differences are reflected in Racah parameter B, and the nephelauxetic effect β. The β coefficient of CaAl2O4:Mn4+ is small, indicating that its orbitals expand greatly, the interaction force between Mn4+ and the host lattice is greater than that of Mn2+.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: IOP Conference Series: Materials Science and Engineering
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
