Abstract
The ZnII atom in the title compound, [Zn(C10H12N3S)2], is N,S-chelated by the deprotonated Schiff base in a tetrahedral environment. The metal atom lies on a twofold rotation axis that relates one anion to the other. The amino H atom forms an intermolecular N—H⋯π interaction to an aromatic ring.
Highlights
The ZnII atom in the title compound, [Zn(C10H12N3S)2], is N,S-chelated by the deprotonated Schiff base in a tetrahedral environment
The metal atom lies on a twofold rotation axis that relates one anion to the other
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: BT5011)
Summary
Key indicators: single-crystal X-ray study; T = 153 K; mean (C–C) = 0.005 A; R factor = 0.039; wR factor = 0.103; data-to-parameter ratio = 18.4. The ZnII atom in the title compound, [Zn(C10H12N3S)2], is N,S-chelated by the deprotonated Schiff base in a tetrahedral environment. The metal atom lies on a twofold rotation axis that relates one anion to the other. The amino H atom forms an intermolecular N—HÁ Á Á interaction to an aromatic ring. Related literature For the two modifications of acetone 4-phenylthiosemicarbazone, see: Jian et al (2005); Venkatraman et al (2005)
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