Abstract
The Ni atom in the title compound, [Ni(C17H15N2O)2]·2C3H7NO, lies on a twofold rotation axis. It is N,O-chelated by the deprotonated Schiff base 2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolate ligand in a square-planar coordination environment. The molecule is linked to a solvent molecule by an indole–dimethylformamide N—H⋯O hydrogen bond.
Highlights
Structure Reports OnlineKey indicators: single-crystal X-ray study; T = 103 K; mean (C–C) = 0.004 A; R factor = 0.049; wR factor = 0.135; data-to-parameter ratio = 16.6
The Ni atom in the title compound, [Ni(C17H15N2O)2]Á2C3H7NO, lies on a twofold rotation axis
The molecule is linked to a solvent molecule by an indole–dimethylformamide N—HÁ Á ÁO hydrogen bond
Summary
Key indicators: single-crystal X-ray study; T = 103 K; mean (C–C) = 0.004 A; R factor = 0.049; wR factor = 0.135; data-to-parameter ratio = 16.6. The Ni atom in the title compound, [Ni(C17H15N2O)2]Á2C3H7NO, lies on a twofold rotation axis. It is N,O-chelated by the deprotonated Schiff base 2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolate ligand in a square-planar coordination environment. The molecule is linked to a solvent molecule by an indole–dimethylformamide N—HÁ Á ÁO hydrogen bond. Crystal data [Ni(C17H15N2O)2]Á2C3H7NO Mr = 731.52 Monoclinic, C2=c a = 38.927 (2) Ab = 5.6999 (3) Ac = 15.7560 (8) A = 98.489 (2)
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