Abstract
The paper describes a theory for constructing electrocatalysts based on immobilized enzymes. High-rate enzymatic electron-transfer reactions in solutions and heterogeneous are analyzed. Macrokinetics of electrocatalysis with enzymes anchored to equiaccessible surface electrodes is discussed, and a number of expressions interrelating electrode potential and current output on the one hand, and kinetic and microkinetic characteristics of the system on the other, are derived.
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