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https://doi.org/10.1021/ol010219y
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Cite Journal: Organic Letters |  Publication Date: Nov 16, 2001 |
 Citations: 180 |
Affiliation: Max-Planck-Institut für Kohlenforschung
[reaction: see text] BINOL-based diphosphonites having achiral backbones are useful ligands in the Rh-catalyzed conjugate addition of arylboronic acids to alpha,beta-unsaturated carbonyl compounds. The nature of the achiral backbone determines the direction and degree of enantioselectivity, with er values of up to 99.5:0.5 possible.
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