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https://doi.org/10.1002/anie.200461624
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Cite Publication Date: Dec 29, 2004 | |
 Citations: 131 |
Affiliation: Max Planck Society, Max-Planck-Institut für Kohlenforschung
Buried in the symmetry: Phosphorylation of ortho-substituted binol derivatives leads to monodentate phosphites (X=OR) or phosphoramidites (X=NR2) having stereogenic centers at phosphorus (see scheme). Such compounds are excellent ligands in rhodium-catalyzed olefin-hydrogenation (95–99 % ee) surpassing the C2-symmetric parent ligands.
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