Abstract
Besser als die Eltern: Die Phosphorylierung ortho-substituierter Binol-Derivate liefert einzähnige Phosphite (X=OR) oder Phosphoramidite (X=NR2) mit Phosphor als stereogenem Zentrum (siehe Schema). Diese Verbindungen sind ausgezeichnete Liganden in Rhodium-katalysierten Olefinhydrierungen (95–99 % ee) – besser als die C2-symmetrischen „Eltern“liganden.
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