Abstract
The determination of reservoir temperatures represents a major task when exploring geothermal systems. Since the uncertainties of classical solute geothermometry are still preventing reliable reservoir temperature estimations, we assess the performance of classical geothermometers and multicomponent geothermometry by applying them to fluids composed from long-term batch-type equilibration experiments and to fluids from natural geothermal springs in the Villarrica area, Southern Chile. The experiments, weathering two reservoir rock analogues from the Villarrica area, highlight a strong impact of reservoir rock composition on the fluid chemistry and, consequently, on calculated in situ temperatures. Especially temperatures calculated from classical solute geothermometry are strongly affected. Multicomponent geothermometry is obviously more robust and independent from rock composition leading to significantly smaller temperature spreads. In a sensitivity analysis, the dilution of geothermal fluid with surficial water, the pH and the aluminum concentration are anticipated to be the factors causing underestimations of reservoir temperatures. We quantify these parameters and correct the results to obtain realistic in situ conditions. Thus, enabling the application of the method also on basis of standard fluid analysis, our approach represents an easy-to-use modification of the original multicomponent geothermometry leading to very plausible subsurface temperatures with significantly low scattering.
Highlights
IntroductionThe in situ temperature is a key parameter for the assessment of geothermal potentials and the economic efficiency of prospected reservoirs
The estimation of reservoir temperatures is a major goal in geothermal exploration
In many cases, the application of different classical solute geothermometer equations leads to a wide range of calculated temperatures
Summary
The in situ temperature is a key parameter for the assessment of geothermal potentials and the economic efficiency of prospected reservoirs. Over more than five decades a large number of solute geothermometers have been established and constantly improved [e.g., Fournier and Rowe (1966), Giggenbach (1988), Can (2002), Sanjuan et al (2014)]. Many of these interrelations, linking the concentration of one constituent or the ratios. Even in studies in which the individual geothermometers has been carefully selected regarding their applicability and validity for the expected conditions, the resulting temperatures show variations of often more than 100 K for the same sample (e.g., Pepin et al 2015; Aquilina et al 2002; Mutlu 1998; D’Amore et al 1994)
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