Abstract
We have measured for the first time the temperature-dependent anisotropic resistivity of several Tl2Ca2Ba2Cu3Ox single crystals. The resistivity ratio between the c axis and the a-b plane orientations in the best crystals is approximately 60 at room temperature. Resistivity data indicate substantial differences in both Tc and the transition width of nominal Tl2Ca2Ba2Cu3Ox plates grown from two different melt compositions. A Tl-O and CuO-rich flux yielded approximately stoichiometric plates with sharp transitions beginning near 113 K, while a Tl-O-rich flux produced plates containing more Tl and less Ba with broad transitions starting near 103 K. These data demonstrate the extreme sensitivity of the superconductivity to cation site disorder in the Tl-Ca-Ba-Cu-O system.
Published Version
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