Analysis of fluorescence properties of novel Eu3+-doped ZnAl2O4-based ceramic aerogels for high-power optical device applications

Abstract

A novel series of ZnAl2O4:Eu3+ aerogels (ZAE) and mullite ceramic phase reinforced ZnAl2O4:Eu3+ aerogels (MZAE) with high fluorescence thermal stability have been firstly synthesized for the encapsulation of high-power optical devices. However, due to the intrinsic structural brittleness of the aerogel, the structure of ZAE tends to collapse during the heat treatment and the fluorescence performance falls short of expectations. To this end, we propose a simple and effective strategy to enhance the structural rigidity of fluorescent aerogels by introducing the mullite ceramic phase into the network structure of ZAE. This can effectively suppress the agglomeration of Eu3+ caused by the collapse of the structure during the heat treatment, thus enhancing the optical properties of the aerogel. Compared with ZAE, MZAE has higher fluorescence thermal stability. The fluorescence intensity of MZAE at 498 K is still 75% of that at 298 K, and the chromaticity shift is only 22×10-3.