Abstract
Radicals which mediate in the reactions of aliphatic carboxylate ions with the sulphate radical-anion, generated from the TiIII–K2S2O8 couple, have been observed by e.s.r. spectroscopy. Both oxidative decarboxylation (RCO2–→ R˙) and hydrogen-atom abstraction from C–H occur. The behaviour of SO4–˙ is compared with that of ·OH.
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Schedule a callMore From: Journal of the Chemical Society, Perkin Transactions 2
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