An elastic organic crystal with multilevel stimuli-responsive room temperature phosphorescence

Abstract

•Elastic organic RTP crystal with multilevel stimuli responsiveness was first reported •Highest RTP quantum yield of 25.1% was recorded in elastic organic RTP crystal •Modulation of RTP was realized via the transition of excited state conformation •RTP single to double emission under external stimuli in single-component system In this work, we report a series of single-component molecules crystals named dialkyl 4,4′-oxalyldibenzoate (n-BZ) with both efficient room temperature phosphorescence (RTP) emission, multilevel stimuli responsiveness, and elasticity or flexibility. The crystalline n-BZ will change from original RTP single emission to RTP dual emission after grinding or thermal annealing (TA). Interestingly, the emission wavelength difference between the RTP dual-emission peaks after grinding or TA reaches 82 nm with emission color changes from cyan blue to orange. In addition, to our knowledge, the largest RTP quantum yield of 25.1% (6-BZ) has been achieved as the highest recorded for organic RTP elastic crystals. Through a series of experiments and theoretical calculations, we demonstrate that the multilevel stimuli responsiveness of n-BZ originates from the transition of excited state conformation and its elasticity from many weak intermolecular interactions, which will provide a molecular design and construction strategy for organic stimuli-responsive RTP materials. In this work, we report a series of single-component molecules crystals named dialkyl 4,4′-oxalyldibenzoate (n-BZ) with both efficient room temperature phosphorescence (RTP) emission, multilevel stimuli responsiveness, and elasticity or flexibility. The crystalline n-BZ will change from original RTP single emission to RTP dual emission after grinding or thermal annealing (TA). Interestingly, the emission wavelength difference between the RTP dual-emission peaks after grinding or TA reaches 82 nm with emission color changes from cyan blue to orange. In addition, to our knowledge, the largest RTP quantum yield of 25.1% (6-BZ) has been achieved as the highest recorded for organic RTP elastic crystals. Through a series of experiments and theoretical calculations, we demonstrate that the multilevel stimuli responsiveness of n-BZ originates from the transition of excited state conformation and its elasticity from many weak intermolecular interactions, which will provide a molecular design and construction strategy for organic stimuli-responsive RTP materials.