Abstract
AFM investigations of a glassy heterogeneous system consisting of an oligomeric cholesteric liquid crystal and the hydrophobic aerosil R812 were carried out. With increasing aerosil concentration, a suppression of the characteristic cholesteric surface pattern was observed. Typical separated aerosil aggregates appear in the samples. Their size and form change from small lumps through bigger rod-like entities to large crystallite-like aggregates of aerosil particles. This matches with observations of light scattering of systems with low molecular mass liquid crystals and of the memory effect. The pitch of the cholesteric fingerprint pattern slightly decreases with increase in the aerosil concentration.
Published Version
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