A suspended 3-omega technique to measure the anisotropic thermal conductivity of semiconducting polymers.

Abstract

Anisotropic thermal conductivity can complicate the performance of semiconducting polymer thin-films in applications such as thermoelectrics and photovoltaics. Anisotropic measurements of low thermal conductivity polymers are challenging, and there are a limited number of appropriate measurement techniques. Suspended film 3-omega is an appropriate technique but has often required unfavorable microfabrication. Herein, we report on the utility of the suspended 3-omega technique that uses shadow masking, and no other microfabrication techniques, in performing anisotropic (in-plane and through-plane) thermal conductivity measurements of polymer films. We report on the necessary conditions for the validity of the 1D suspended-film heat transfer model and provide experimental guidelines for in-plane thermal conductivity measurements of polymer thin-films. Furthermore, for the first time, we report the anisotropic thermal conductivities of N2200 and a low molecular weight P3HT, which are two common n-type and p-type semiconducting polymers. Measured thermal conductivities are compared with predictions from the conventional Cahill-Pohl model and a recent empirical model that more accurately predicts the temperature dependence.