Abstract

Transference and solvation phenomena for the ions of hydrochloric acid in water, 99·7 weight per cent ethanol, and water-ethanol solvents have been studied. The transference number of the cation as a function of acid concentration in water and in 99·7 weight per cent ethanol and as a function of solvent composition are presented graphically and discussed in relation to Grotthus and ordinary conduction of the hydrogen ion and in relation to relative solvation of hydrogen and chloride ions. The amount of solvent transferred from anode to cathode is also presented graphically and discussed in relation to the transference numbers of the ions.

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