Abstract
Fine-grained ceramics based on solid solutions of ZrO2-x-Ln2O3 (where Ln = Sm, Yb), which are used to simulate inert matrix fuel (IMF), were obtained by colloidal chemical synthesis of powders and their Spark Plasma Sintering (SPS). It has been established that the SPS activation energy (Qs) for fine-grain ceramics based on ZrO2 corresponds to the activation energy of oxygen diffusion on grain boundaries of zirconium oxide (zirconia). We have demonstrated that introducing oxides of samarium (Sm2O3) and ytterbium (Yb2O3) into zirconia decreases SPS activation energy and stabilizes the phase composition of zirconia. Ceramics with densities up to 100% were obtained by the following modes of SPS: sintering temperature 1000–1250 °C, sintering time 6–10 min. Hydrolysis testing in the static mode (Т = 20 °C, P = 1 atm) in distilled water revealed no leaching of lanthanide ions at detection thresholds of 5 ppm for Sm ions and 0.1 ppm for Yb ions.
Published Version
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