Abstract

The promotion of the extraction rate of iron by TTA-benzene in the presence of ammonium thiocyanate was previously attributed to the rapid extraction of Fe(SCN) 3 and the subsequent replacement of SCN − by TTA − in the organic phase. The replacement of the benzene solvent by a benzene-hexone mixture was found to yield both an even greater enhancement of the extraction rate and a definite synergism. It was confirmed that these effects are attributable to the mechanism previously proposed.

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