Abstract
A silver(I) coordination polymer (CP), {[Ag(DCTP)0.5(bpy)(H2O)]·0.5H2O}n (1) based on 2,5-dichloroterephthalic acid (H2DCTP) and 4,4′-bipyridine (bpy) were synthesized under hydrothermal condition. CP 1 features a 1D infinite undulating ladder-like chain, which is further extended into a 3D supramolecular network through classic O–H⋯O hydrogen bond interactions. CP 1 exhibits highly selective and sensitive luminescent detection for Cr2O72− in aqueous solution with quenching efficiency up to 2.00 × 104 M−1 and a low detection limit of 2.06 µM. Further, Hirshfeld surface analyses and the photocatalytic properties of CP 1 have also been investigated in detail. Remarkably, CP 1 presented a rare example of Ag(I)-based CP as luminescent probe and photocatalytic materials simultaneously.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
