Abstract
AbstractThree silver(I) coordination polymers namely, [Ag4(L1)2(1, 4‐ndc)2]n (1) {[Ag(L2)]·(1, 4‐Hndc)·H2O}n (2), and {[Ag(L3)(H2O)]·(1, 4‐Hndc)}n (3) [L1 = 1, 3‐bis(benzimidazol‐1‐ylmethyl)benzene, 1, 4‐H2ndc = 1, 4‐naphthalenedicarboxylic acid, L2 = 1, 3‐bis(5, 6‐dimethylbenzimidazole‐1‐ylmethyl)benzene, L3 = 1, 4‐bis(5, 6‐dimethylbenzimidazole)butane], were hydrothermally synthesized and characterized by single‐crystal X‐ray diffraction analysis, elemental analysis, IR spectroscopy, thermogravimetric and XRPD analysis. Complex 1 displays a 1D tube‐like chain, which is packed into a 3D supramolecular network by π–π stacking interactions. Complex 2 features an infinite 1D linear chain. Complex 3 contains a 1D wave‐like chain, which is extended into a 3D supramolecular network through O–H···O hydrogen bonding interactions. Moreover, these coordination polymers exhibit catalytic properties for degradation of methyl orange in Fenton‐like processes.
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