Abstract
Two Ag(I) coordination polymers, {[Ag(bib)0.5]Cl·4H2O} n (1) with a 1D zigzag chain structure extended into a 3D supramolecular network by face-to-face π–π stacking interactions, and [Ag(bib)(Hpydca)] n (2) with the first example of three-connected uninodal fourfold interpenetrating ths network via hydrogen-bonding interactions (bib = 1,4-bis(benzimidazole)butane, pydca = pyridine-2,6-dicarboxylate) were synthesized under hydrothermal conditions and characterized by elemental analysis, IR, thermogravimetric analysis and single crystal X-ray diffraction. In addition, the fluorescence properties of 1 and 2 in the solid state were investigated at room temperature.
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More From: Journal of Inorganic and Organometallic Polymers and Materials
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