Abstract
A large-eddy simulation is performed on a turbulent dispersion of chemically reactive air pollutants in a two-dimensional urban street canyon with an aspect ratio of 1.0. Nitrogen monoxide emitted from a line-source set on the bottom of the street canyon disperses and reacts with Ozone included in a free stream. The reactions have significant influences on the concentrations of pollutants in the canyon space, and they increase the concentrations of the reaction products relative to of the concentrations of the reactants. The transport of air pollutants through a free shear layer above the canyon is closely related to the structure of the turbulence. Gases in the canyon are mainly exhausted when low-speed regions appear above the canyon. In contrast, pollutants in the free stream flow into the canyon with high-speed fluid bodies. Consequently, the correlation between the time fluctuations of the reactants' concentrations strongly affects the reaction rates in the region near the free shear layer. In this calculation, the correlation term reaches to a value of 20% of the mean reaction rate at a maximum there.
Published Version
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