Abstract
A novel ES-BGK-based model of non-polytropic rarefied gases in the framework of kinetic theory is presented. Key features of this model are: an internal state density function depending only on the microscopic energy of internal modes (avoiding the dependence on temperature seen in previous reference studies); full compliance with the H-theorem; feasibility of the closure of the system of moment equations based on the maximum entropy principle, following the well-established procedure of rational extended thermodynamics. The structure of planar shock waves in carbon dioxide (CO2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_2$$\\end{document}) obtained with the present model is in general good agreement with that of previous results, except for the computed internal temperature profile, which is qualitatively different with respect to the results obtained in previous studies, showing here a consistently monotonic behavior across the shock structure, rather than the non monotonic behavior previously found.
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