A new method for reducing impurities in clay minerals

Abstract

The processing of clay minerals consists, among other steps, in the removal of isolated mineral impurities, that is, not associated to crystalline structure of clay minerals, such as fractions of quartz and feldspars, originating from the process of soil formation. Thus, this work evaluated a sustainable method to reduction of isolated mineral impurities, in 4 in natura soil samples from Maranhão/Brazil, containing clay minerals. The method consisted of dispersing the samples only in water under high rotation and separating the impurities by sieving and decanting. The water and clay fraction were recovered from a manufactured solar evaporator and the clay fraction analyzed: X-ray diffraction (XRD) revealed a reduction in the intensities of mineral impurities, largely quartz, and a significant increase in the intensity corresponding to clay minerals; X-ray fluorescence (XRF) demonstrated a decrease in the SiO2/Al2O3 ratio, indicating quartz removal; Fourier transform infrared analysis (FTIR) indicated removal of organic material; thermal analysis (TG/DTG) revealed an increase in the percentage of structural water loss, suggesting an increase in clay mineral content, and adsorption/desorption isotherms of N2 demonstrated an increase in the surface areas and adsorption capacity of the benefited samples. The process yields obtained demonstrated compatibility with the particle size of the samples, with more expressive results for the more clayey ones. Thus, the investigated method, low cost and sustainable, proved to be viable and effective in obtaining clay minerals with reduced presence of isolated impurities, promoting considerable improvements in their properties, and favoring various technological applications, such as adsorption, heterogeneous catalysis, synthesis of mesoporous materials, among others.